Hi,
我不太了解DirectX编程。在windows store app中，.hlsli文件经VS编译后应该会变成.cso文件。当你打开或者load .hlsli文件时，您应该不是以dll的形式使用它，您应该将它包含在AppX Package里面，具体您可以参考：
http://social.msdn.microsoft.com/Forums/windowsapps/en-US/69f17e7e-fccf-4b7b-9d31-d9af6e231a12/trouble-loading-a-shader-file?forum=wingameswithdirectx
祝您好运！
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