EWS is a Mailbox access API so it can only be used to get the ACL's on a particular Mailbox Folder or Mailbox delegate permissions.
The DACL for the Mailbox that controls Mailbox access eg FullAccess etc and also SendAs permissions (which is the AD DACL) can only be access either via Remote Powershell and the Exchange Management Shell cmdlets (this is the recommended/supported
method) or directly via LDAP accessing the AD object.
EWS is not an API that you can use to adminster an Exchange Mailbox/Server for this you should use the Exchange Management Shell.
Cheers
Glen