Hi Tsql,
According to your expression, it seems that you want to display the percent value that the corresponding "MV" value of each "Name" accounts for the total value of "MV". In this case, you can achieve it refer to the steps below:
1. Right-click your chart, and select “Show Data Labels”.
2. Right-click the data labels, select “Series Label Properties”.
3. Click the expression button and type in the expression below:
=fields!Nmae.Value & FormatPercent(sum(fields!MV.Value)/Sum(Fields!mv.Value, "DataSet1"),2)
The reports looks like below:

If you have any questions, please feel free to ask.
Regards,
Charlie Liao