An index which one way or the other is a unique index will have 1 for the is_unique column.
An index might have been defined with a Primary Key constraint, and such index will also have 1 in the is_primary_key column.
An index might have been defined with a Unique constraint, and such index will also have 1 in the is_unique_constraint column.
Check out http://msdn.microsoft.com/en-us/library/ms190765.aspx for more information about constraints.
Tibor Karaszi, SQL Server MVP | http://www.karaszi.com/sqlserver/default.asp | http://sqlblog.com/blogs/tibor_karaszi