Hi,
If you're using a lookup field at the table level, you should consider changing it to a regular textbox. I think to get what you want, you can set the Row Source property of a combobox on a form using its GotFocus event. For example, you might try something
like:
Me.ComboboxName.RowSource = "Not Started;In Progress" & IIf(IsNull([Purchase Order]), ";Paid", "") & ";Not Paid"
Hope it helps...