Most likely due to a print driver corrupting the process memory. Which print drivers are installed on the machine? Most likely the spooler service is failing as it loads the driver files, you cannot use the spooler service to determine this data.
you can find the drivers in the registry
on 64bit under
HKEY_LOCAL_MACHINE\SYSTEM\CurrentControlSet\Control\Print\Environments\Windows x64\Drivers
on 32bit under
HKEY_LOCAL_MACHINE\SYSTEM\CurrentControlSet\Control\Print\Environments\Windows NT x86\Drivers
Alan Morris Windows Printing Team