Hi,
how did you create the PDF? Maybe you can print to the MXDW, and have an XPS right away.
You can also print the PDF to XPS, but you need an app that can print PDF. Alternatively you'll need a library that converts PDF to XPS.
For the comparison: you could render the XPS files to raster, and check the rasters for differences.
This is of course a pure visual comparison.
(We do this as part of our regression testing here @ NiXPS)
If you would want a structural diff, you would do so by comparing the components of each XPS individually.
Of course, this will only yield satisfying results if the XPS files are not very 'structurally different'.
Regards,
Nick.
Check out my cross platform xps library and tools at http://nixps.com