I assume you're talking about doing this without hardcoding the assembly name into the file. You can use a combination of Assembly.GetExecutingAssembly().Location and OpenExeConfiguration to fetch the Configuration object for your specific running assembly.
string path = Assembly.GetExecutingAssembly().Location;
Configuration config = ConfigurationManager.OpenExeConfiguration(path);
string value = config.AppSettings.Settings["value"].Value;
David Morton -
http://blog.davemorton.net/